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Again, we are motivated by convenience and the physical nature of the problem. Equation (21. An electrodiffusive component ΦE is present, it is given by the Nernst-Plank relationship by ΦE (S)(Ps SΨzF)RT (6) where F is the Faraday constant and R is the gas constant. If Z 0,thentheboundaryconditionisthatforaPECnˆ×Eˇ 0.

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